Concepedia

Dichlorocarbene Complexes of Iron(II)‐Porphyrins–Crystal and Molecular Structure of Fe(TPP)(CCl<sub>2</sub>)(H<sub>2</sub>O)

Daniel Mansuy, M. Lange, J.C. Chottard, J.F. Bartoli, Bernard Chevrier, Raymond Weiss

Angewandte Chemie International Edition in English · 1978 · 99 citations · 5 references

DOI

Concepts

Abstract

The structure of an iron porphyrin with dichlorocarbene as ligand has now been estabished by X-ray analysis. The complex (1) accordingly contains a planar Fe(TPP)skeleton with H2O and CCl2 as axial ligands. The structural unit (2) is almost linear.

References

5

Trends in metalloporphyrin stereochemistry

W. Robert Scheidt · Accounts of Chemical Research · 1977 · 131 citations

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Spectroscopic and structural characterization of ruthenium(II) carbonyl-porphine complexes

J. J. Bonnet, Sandra S. Eaton, Gareth R. Eaton et al. · Journal of the American Chemical Society · 1973 · 126 citations

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Nitrosylmetalloporphyrins. III. Synthesis and molecular stereochemistry of nitrosyl-.alpha.,.beta.,.gamma.,.delta.-tetraphenylporphinato(1-methylimidazole)iron(II)

W. Robert Scheidt, P.L. Piciulo · Journal of the American Chemical Society · 1976 · 123 citations

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Stereochemistry of low-spin iron porphyrins. II. Bis(piperidine)-.alpha.,.beta.,.gamma.,.delta.-tetraphenylporphinatoiron(II)

Lewis J. Radonovich, Allen Bloom, J. L. Hoard · Journal of the American Chemical Society · 1972 · 103 citations

, , +7

The mechanism of halothane binding to microsomal cytochrome P450

Daniel Mansuy, Wolfgang Nastainczyk, V. Ullrich · Naunyn-Schmiedeberg s Archives of Pharmacology · 1974 · 88 citations

, , +14