The Symmetrical Top in the Undulatory Mechanics

R. de L. Kronig, I. I. Rabi

Physical Review · 1927 · 76 citations · 2 references

Concepts

Abstract

Schr\"odinger's method for determining the energy levels of an atomic system is applied to the case of the symmetrical top (moment of inertia about axis of symmetry $C$, the other one $A$). The energy values are found to be ${W}_{\mathrm{jn}}=\frac{{h}^{2}}{8{\ensuremath{\pi}}^{2}}\left[\frac{1}{A}j(j+1)+\left(\frac{1}{C}\ensuremath{-}\frac{1}{A}\right){n}^{2}\right]$ in agreement with the result obtained by Dennison from the matrix mechanics. The quantum numbers $j$ and $n$ must be integers restricted by $0\ensuremath{\leqq}j$, $|n|\ensuremath{\leqq}j$, while half-integral values are not permissible. The intensities of transitions are also calculated.

References

2