Chemical Communications · 2012 · 131 citations · 40 references
Natural SciencesChemical EngineeringChemistryCatalysisCatalyst DesignCatalyst SynthesisCatalytic MaterialsCatalytic MechanismsMetal CatalysisRadical ReactionsC - C Coupling CatalysisC - C Coupling ReactionsC-c Coupling CatalysisCopper-catalyzed CouplingDecarboxylative Cross-couplingPalladium CatalystsRadical Mediated C - H FunctionalizationTransition-metal-catalyzed Functionalization
We have successfully developed an example of copper-catalyzed decarboxylative C(sp(2))-C(sp(3)) coupling reactions via C-H functionalization for the first time. It is noteworthy that our catalytic system is very stable, low-cost, palladium-free, ligand-free, and easily accessible.
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Synthesis of Biaryls via Catalytic Decarboxylative Coupling
Lukas J. Gooßen, Guo‐Jun Deng, Laura M. Levy · Science · 2006 · 946 citations