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Oxidative activation of Co<sup>II</sup>in Schiff base complexes in the presence of n-butyltin trichloride: the molecular structure of Bu<sup>n</sup>Sn(OMe)Cl<sub>2</sub>·CoCl(salen)[salen =N,N′-ethylenebis(salicylideneaminato)]
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1985
Year
Inorganic ChemistryChemical EngineeringSchiff Base ComplexesEngineeringCrystal StructureBiochemistryOxidative ActivationNatural SciencesCoordination ComplexMolecular ComplexSchiff Base SpeciesChemistryInorganic SynthesisBiomolecular EngineeringInorganic Compound
Air stable chloroform solutions of Schiff base complexes of CoII undergo rapid cobalt oxidation on addition of n-butyltin trichloride yielding complexes in which, as exemplified by the crystal structure of BunSn(OMe)Cl2·CoCl-(salen)[salen =N,N′-ethylenebis(salicylideneaminato)], the cobalt(III) Schiff base species behave as Lewis bases towards tin(IV).