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Chemistry of acetylenic ethers XLVI: Addition of thiols to acetylenic ethers
41
Citations
15
References
1960
Year
Free‐radical AdditionChemical EngineeringEngineeringAlkene MetathesisRadical (Chemistry)Produces Much CisOrganic ChemistryChemistryAcetylenic EthersNatural Product SynthesisOther ThiolsSynthetic ChemistryEnantioselective SynthesisBiomolecular Engineering
Abstract The free‐radical addition of ethanethiol to ethoxyethyne produces much cis and a little trans 1‐ethoxy‐2‐(ethylthio)ethene, whereas the nucleophilic addition of sodium ethanethiolate yields 1‐ethoxy‐1‐(ethylthio)ethene. The same applies to additions of other thiols.
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