Zeitschrift für Naturforschung B · 1976 · 28 citations · 0 references
Natural SciencesChemistryMaterials ScienceElectrochemistryInorganic ChemistryPhysical ChemistryElectrode KineticsElectrode MaterialsElectrode-electrolyte InterfacesElectrolyte MaterialsElectrolyte SolutionsSolid-state ElectrolytesCathodic ReductionCathodic Reduction ProcessesElectrochemical Reaction MechanismsElectrolyte ChemistryElectrolyte Solution ThermodynamicsInterlayer MaterialsIonic Radius EffectsThermodynamics Of Electrolyte Solutions
Cathodic reduction of MoS 2 in DMSO electrolytes containing alkali cations A + results in the formation of defined ternary phases A+ 0.125 (DMSO) y [MoS 2 ] 0.125 - with highly mobile solvated interlayer cations. Reduction of MoS 2 in DME electrolytes yields similar products. Basal spacings are dependant on solvent type and on ionic radius of A + . Further reduction of these compounds is associated with irreversible processes.