Concepedia

Remarkable regioselectivity in the preparation of the first heterotrimetallic MoW⋯Cr chain

Michael Nippe, George H. Timmer, John F. Berry

Chemical Communications · 2009 · 44 citations · 19 references

DOI

Concepts

Abstract

Addition of CrCl(2) to the dinuclear synthon MoW(dpa)(4) yields a regioselectively formed heterotrimetallic Mo[quadruple bond]W...Cr chain; computational studies suggest that the polarization of the Mo[quadruple bond]W quadruple bond partially accounts for this unexpected selectivity.

References

19

Molecular and Electronic Structures by Design:  Tuning Symmetrical and Unsymmetrical Linear Trichromium Chains

John F. Berry, F. Albert Cotton, Tong‐Bu Lu et al. · Journal of the American Chemical Society · 2004 · 131 citations

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Introducing a Metal−Metal Multiply Bonded Group as an “Axial Ligand” to Iron:  Synthetic Design of a Linear Cr−Cr···Fe Framework

Michael Nippe, John F. Berry · Journal of the American Chemical Society · 2007 · 85 citations

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Structural, Magnetic, and Theoretical Characterization of a Heterometallic Polypyridylamide Complex

Marie‐Madeleine Rohmer, Isiah Po‐Chun Liu, Jheng‐Cheng Lin et al. · Angewandte Chemie International Edition · 2007 · 82 citations

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Heterobimetallic Main‐Group–Transition‐Metal Paddle‐Wheel Carboxylates

Evgeny V. Dikarev, Thomas Gray, Bo Li · Angewandte Chemie International Edition · 2005 · 77 citations

, , +9

Remarkable Effects of Axial π* Coordination on the Cr−Cr Quadruple Bond in Dichromium Paddlewheel Complexes

F. Albert Cotton, L.M. Daniels, C.A. Murillo et al. · Journal of the American Chemical Society · 1999 · 66 citations

, , +14