Concepedia

Iridium-Catalyzed Ring Cleavage Reaction of Cyclobutanone <i>O</i>-Benzoyloximes Providing Nitriles

Takahiro Nishimura, Tomoaki Yoshinaka, Yoshiki Nishiguchi, Yasunari Maeda, Sakae Uemura

Organic Letters · 2005 · 145 citations · 14 references

DOI

Concepts

Abstract

[reaction: see text] Iridium-catalyzed ring cleavage reaction of cyclobutanone O-benzoyloximes in the presence of 9,10-dihydroanthracene and potassium carbonate proceeds to give saturated nitriles via C-C bond fission at the sterically more hindered site.

References

14

Standing Wave Enhancement of Red Absorbance and Photocurrent in Dye-Sensitized Titanium Dioxide Photoelectrodes Coupled to Photonic Crystals

Suzushi Nishimura, Neal M. Abrams, Bradley A. Lewis et al. · Journal of the American Chemical Society · 2003 · 596 citations

, , +13

Palladium(II)-Catalyzed Oxidative Ring Cleavage of <i>tert</i>-Cyclobutanols under Oxygen Atmosphere

Takahiro Nishimura, Kouichi Ohe, Sakae Uemura · Journal of the American Chemical Society · 1999 · 204 citations

, , +7

Palladium(0)-Catalyzed Ring Cleavage of Cyclobutanone Oximes Leading to Nitriles via β-Carbon Elimination

Takahiro Nishimura, Sakae Uemura · Journal of the American Chemical Society · 2000 · 171 citations

, , +9

Palladium‐Catalyzed Asymmetric Arylation, Vinylation, and Allenylation of tert‐Cyclobutanols via Enantioselective C‐C Bond Cleavage.

Satoshi Matsumura, Yasunari Maeda, Takahiro Nishimura et al. · ChemInform · 2003 · 163 citations · Full text

, , +12

Palladium-Catalyzed Arylation of <i>tert</i>-Cyclobutanols with Aryl Bromide via C−C Bond Cleavage:  New Approach for the γ-Arylated Ketones

Takahiro Nishimura, Sakae Uemura · Journal of the American Chemical Society · 1999 · 163 citations

, , +11