Synthesis of Thermally Stable Extra-Large Pore Crystalline Materials: A Uranyl Germanate with 12-Ring Channels

Chia‐Hui Lin, Ray‐Kuang Chiang, Kwang‐Hwa Lii

Journal of the American Chemical Society · 2009 · 41 citations · 20 references

Concepts

Abstract

A thermally stable extra-large pore uranyl germanate is synthesized under high-temperature, high-pressure hydrothermal conditions at 585 degrees C and 150 MPa. The structure contains U(6+)O(6) tetragonal bipyramids which are interconnected by digermanate groups to form a 3D framework with 12-ring pore openings.

References

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