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Aurophilicity at Sulfur Centers: Synthesis and Structure of the Tetragold(<scp>I</scp>) Species [(Ph<sub>3</sub>PAu)<sub>4</sub>S](CF<sub>3</sub>SO<sub>3</sub>)<sub>2</sub> · 2CH<sub>2</sub>Cl<sub>2</sub>
90
Citations
11
References
1994
Year
Inorganic CompoundInorganic ChemistryEngineeringBiochemistryTheoretical Inorganic ChemistryNatural SciencesCoordination ComplexAu AtomsPr3 Au LigandsMolecular BiologyAtomic PhysicsMain Group ChemistrySulfur CentersChemistryCrystallographyInorganic SynthesisBiophysicsApical Position
More than three PR3 Au ligands were coordinated for the first time to an element of the sixth main group: the μ4-S atom of the title compound occupies the apical position in the tetragonal pyramidal framework (shown on the right); its four Au atoms are arranged in a butterfly form with a hinge angle of 30°.
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