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Towards Main-Chain-Polyoxometalate-Containing Hybrid Polymers: A Highly Efficient Approach to Bifunctionalized Organoimido Derivatives of Hexamolybdates
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2002
Year
EngineeringBifunctionalized Organoimido DerivativesOrganic ChemistryChemistryPolymersHexamolybdate AnionsIon 1Hybrid MaterialsPolymer ChemistryMaterials ScienceMain-chain-polyoxometalate-containing Hybrid PolymersOrganometallic PolymerOrganic Material ChemistryPolymer ScienceHighly Efficient ApproachInorganic PolymerMolybdenum BlocksPolymer ReactionSynthetic ChemistryPolymer HybridPolymer Synthesis
Molybdenum blocks in organic polymers: Bifunctionalized hexamolybdate anions (such as 1) can be selectively synthesized in high yields by using the octamolybdate anion 2 as the starting material. The ion 1 can then be used in the synthesis of the first main-chain-polyoxometalate-containing hybrid polymer.