Towards Main-Chain-Polyoxometalate-Containing Hybrid Polymers: A Highly Efficient Approach to Bifunctionalized Organoimido Derivatives of Hexamolybdates

Abstract

Molybdenum blocks in organic polymers: Bifunctionalized hexamolybdate anions (such as 1) can be selectively synthesized in high yields by using the octamolybdate anion 2 as the starting material. The ion 1 can then be used in the synthesis of the first main-chain-polyoxometalate-containing hybrid polymer.