The influence of BaCuO₂addition in Gd–Ba–Cu–O single-grain superconductors fabricated in air

Abstract

High quality Gd–Ba–Cu–O single-grain bulks with different BaCuO2−δ adding contents were grown in air via a hot-seeding melt process. At 77 K, all samples show a well-developed secondary peak effect with high Jc values, which are comparable to that of OCMG-processed Ga–Ba–Cu–O samples. The BaCuO2−δ addition can effectively suppress the Gd–Ba substitution and therefore enhance the superconducting properties. For the sample with a composition of Gd123:BaCuO2−δ = 1:0.3 in a molar ratio, the Jc(B = 0) and Jc,peak(B = 1.3 T) reach 6.45 × 104 A cm−2 and 6.04 × 104 A cm−2, respectively, which are the record high Jc values at 77 K for Gd–Ba–Cu–O samples melt processed in air.