Publication | Open Access
Magnesium−Magnesium Bond Stabilized by a Doubly Reduced α-Diimine: Synthesis and Structure of [K(THF)<sub>3</sub>]<sub>2</sub>[LMg−MgL] (L = [(2,6-<sup><i>i</i></sup>Pr<sub>2</sub>C<sub>6</sub>H<sub>3</sub>)NC(Me)]<sub>2</sub><sup>2−</sup>)
123
Citations
16
References
2009
Year
Inorganic ChemistryMagnetic PropertiesMg-mg Bond LengthAlpha-diimine LigandEngineeringMagnesium−magnesium Bond StabilizedNew Mg-mg-bonded CompoundCoordination ComplexMagnesium-based CompositeDoubly Reduced α-DiimineChemistryPharmacologyCrystallographyInorganic SynthesisBiomolecular EngineeringInorganic Compound
A new Mg-Mg-bonded compound stabilized by a doubly reduced alpha-diimine ligand, [K(THF)(3)](2)[LMg-MgL] (L = [(2,6-(i)Pr(2)C(6)H(3))NC(Me)](2)(2-)), has been synthesized and characterized by single-crystal X-ray diffraction and density functional theory analysis. The Mg-Mg bond length is 2.9370(18) A.
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