Application of the many‐body perturbation theory by using localized orbitals

Abstract

Abstract Diagrammatic formulation of the many‐body perturbation theory is investigated when both the occupied orbitals and the virtual ones are localized, i.e., they are unitary transforms of the canonical Hartree–Fock orbitals. All diagrams representing ground state correlation energy can be generated through fifth order. For cyclic polyenes C 6 H 6 and C 10 H 10 as model systems, the energy corrections are calculated in the Pariser–Parr–Pople approximation for a wide range of the coupling constant β −1 , through fourth order including some fifth order terms. The results are compared to those obtained by other methods: perturbation theory by using canonical orbitals and full CI. The effect of neglecting contributions from orbitals localized into neighboring sites is also studied.