Inorganic Chemistry · 2001 · 52 citations · 21 references
Natural SciencesChemical EngineeringChemistryCrystal StructureInorganic ChemistrySolid-state ChemistryCluster ChemistryCluster CompoundsCoordination ChemistryCoordination PolymersCrystal EngineeringPolymer StructureCluster SynthesisCoordination Polymer SynthesisHydrothermal SynthesisMolecular ClustersStructural Characterization Of ClustersSupramolecular Coordination ComplexesThree-dimensional Coordination PolymersTransition Metal Clusters
The hydrothermally synthesized Co7(μ3-OH)8(μ-ox)3(μ-ppz)3 contains heptanuclear hydroxo-bridged Co(II) clusters in the form of corner-fused double cubanes. Each cluster is further bridged by six oxalate (ox) and six piperazine (ppz) ligands with 12 other clusters into a 3-D structure.
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Design and synthesis of an exceptionally stable and highly porous metal-organic framework
Hailian Li, Mohamed Eddaoudi, M. O’Keeffe et al. · Nature · 1999 · 8.4K citations · Full text