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Hydrothermal Synthesis and Structural Characterization of a Coordination Polymer Containing Heptanuclear Co<sub>7</sub>(μ<sub>3</sub>-OH)<sub>8</sub> Clusters
52
Citations
21
References
2001
Year
Materials ScienceInorganic ChemistryStructural CharacterizationCorner-fused Double CubanesEngineeringCoordination ComplexPolymer ScienceOther Clusters3-D StructureCoordination PolymerChemistryHydrothermal SynthesisInorganic SynthesisPolymer ChemistryInorganic Compound
The hydrothermally synthesized Co7(μ3-OH)8(μ-ox)3(μ-ppz)3 contains heptanuclear hydroxo-bridged Co(II) clusters in the form of corner-fused double cubanes. Each cluster is further bridged by six oxalate (ox) and six piperazine (ppz) ligands with 12 other clusters into a 3-D structure.
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