Concepedia

Solvent and temperature effect in aldol condensation between the lithium enolate of tert-butyl acetate and 2-phenyl propanal: enthalpy and entropy contribution

Gianfranco Cainelli, Paola Galletti, Daria Giacomini, Paolo Orioli

Tetrahedron Letters · 2001 · 15 citations · 14 references

DOI

Concepts

References

14

The Activated Complex in Chemical Reactions

Henry Eyring · The Journal of Chemical Physics · 1935 · 5.7K citations

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Acyclic stereoselection. 16. High diastereofacial selectivity in Lewis acid mediated additions of enol silanes to chiral aldehydes

Clayton H. Heathcock, Lee A. Flippin · Journal of the American Chemical Society · 1983 · 164 citations

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Entropy-Controlled Asymmetric Photochemistry:  Switching of Product Chirality by Solvent

Yoshihisa Inoue, Haruhiko Ikeda, Masayuki Kaneda et al. · Journal of the American Chemical Society · 1999 · 131 citations

, , +9

Lithium Diisopropylamide-Mediated Enolizations:  Solvent-Independent Rates, Solvent-Dependent Mechanisms

Xiufeng Sun, David B. Collum · Journal of the American Chemical Society · 2000 · 86 citations

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Entropy-Controlled Selectivity in the Vinylation of a Cyclic Chiral Nitrone. An Efficient Route to Enantiopure Polyhydroxylated Pyrrolidines

Marco Lombardo, Serena Fabbroni, Claudio Trombini · The Journal of Organic Chemistry · 2001 · 77 citations

, , +13