X-Ray Scattering from Liquid Crystals. I. Cholesteryl Nonanoate and Myristate

Abstract

X-ray scattering intensities from unoriented samples of cholesteryl nonanoate and myristate are reported for several temperatures in the smectic $A$, cholesteric, and isotropic liquid phases. The measured Bragg-scattering intensities from the smectic planes are used to test a recent theoretical model of the smectic $A$ phase. Strong pretransition scattering (short-range-order or order-parameter fluctuations) are observed in the cholesteric phase and a Landau theory is constructed to describe this effect.