Concepedia

Recent Sulphone-Based Olefination Reactions

Philip Kocieński

Phosphorous and Sulfur and the Related Elements · 1985 · 90 citations · 39 references

DOI

Concepts

Abstract

Abstract The scope, limitations, and recent applications of two olefination reactions based on the reductive elimination of β-acyloxy sulphones (the Julia olefination) and the fluoride-induced elimination of β-trimethylsilyl sulphones is reviewed.

References

39

Allylic sulfoxides. Useful intermediates in organic synthesis

David A. Evans, Glenn C. Andrews · Accounts of Chemical Research · 1974 · 525 citations

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Desulfonylation of aryl alkyl sulfones

Barry M. Trost, Henry C. Arndt, Paul E. Strege et al. · Tetrahedron Letters · 1976 · 284 citations

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Scope and stereochemistry of an olefin synthesis from β-hydroxysulphones

Philip Kocieński, B. Lythgoe, S. RUSTON · Journal of the Chemical Society Perkin Transactions 1 · 1978 · 182 citations

, , +7

Dienophilic properties of phenyl vinyl sulfone and trans-1-(phenylsulfonyl)-2-(trimethylsilyl)ethylene. Their utilization as synthons for ethylene, 1-alkenes, acetylene, and monosubstituted alkynes in the construction of functionalized six-membered rings via [4 + 2] .pi. cycloaddition methodology

Richard V. C. Carr, Richard Vaughan Williams, Leo A. Paquette · The Journal of Organic Chemistry · 1983 · 120 citations

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The influence of chain-branching on the steric outcome of some olefin-forming reactions

Philip Kocieński, B. Lythgoe, Ian Waterhouse · Journal of the Chemical Society Perkin Transactions 1 · 1980 · 103 citations

, , +12