Concepedia

Dramatic Solvent Effects on the Absolute Rate Constants for Abstraction of the Hydroxylic Hydrogen Atom from tert-Butyl Hydroperoxide and Phenol by the Cumyloxyl Radical. The Role of Hydrogen Bonding

David V. Avila, K. U. Ingold, J. Lusztyk, William H. Green, D. R. Procopio

Journal of the American Chemical Society · 1995 · 143 citations · 0 references

Concepts

Natural SciencesChemistryCatalysisChemical KineticsOrganic ChemistryChemical BondingHydrogen AtomMolecular BondingRadical ReactionsSolvation EffectsHydrogen Bonding EffectsRate ConstantsSolvent EffectsSolvent Effects On PkaSolvent Effects On Reaction MechanismsSolvent Effects On Reaction Rates

Abstract

Peer reviewed: Yes