Selective 1,2-addition of organocerium(III) reagents to α,β-unsaturated carbonyl compounds

Lanthanoids in organic synthesis. 6. Reduction of .alpha.-enones by sodium borohydride in the presence of lanthanoid chlorides: synthetic and mechanistic aspects

André Luís Gemal, Jean Louis Luche · Journal of the American Chemical Society · 1981 · 1K citations

Natural Sciences, Chemistry, Inorganic Chemistry +5

Organocerium reagents. Nucleophilic addition to easily enolizable ketones

Tsuneo Imamoto, Yasushi Sugiura, Nobuyuki Takiyama · Tetrahedron Letters · 1984 · 268 citations

Natural Sciences, Chemistry, Medicinal Chemistry +10

Mechanisms of Grignard reagent addition to ketones

E. C. Ashby, J. Laemmle, H. M. Neumann · Accounts of Chemical Research · 1974 · 127 citations

Natural Sciences, Chemistry, Analytical Chemistry +7

The Appearance of Free Radicals during Grignard Reactions

Kazuhiro Maruyama · Bulletin of the Chemical Society of Japan · 1964 · 50 citations

Natural Sciences, Chemistry, Physics +5

Reactions involving electron transfer. VI. Stereochemical test for anion radical intermediates in additions to carbonyl compounds

Herbert O. House, Paul D. Weeks · Journal of the American Chemical Society · 1975 · 46 citations

Natural Sciences, Chemistry, Analytical Chemistry +12