Concepedia

Preparation and crystal structure of tris(hexacarbonyldicobalt-π-ethynyl)arsine: [(CO)6Co2C2H]3As

Journal of the Chemical Society D Chemical Communications · 1970 · 18 citations · 0 references

Concepts

Inorganic CompoundInorganic ChemistryCrystal StructureSingle-crystal X-ray AnalysisEngineeringHexacarbonyldicobalt FragmentsOrganic ChemistryOrganometallic CatalysisChemistrySupramolecular ChemistryCrystallographyInorganic SynthesisBiomolecular EngineeringAir-stable Complex

Abstract

Dicobalt octacarbonyl reacts with triethynylarsine to produce a crystalline, air-stable complex, shown by single-crystal X-ray analysis to have three hexacarbonyldicobalt fragments π-bonded to the ethynyl groups.

Preparation and crystal structure of tris(hexacarbonyldicobalt-π-ethynyl)arsine: [(CO)<sub>6</sub>Co<sub>2</sub>C<sub>2</sub>H]<sub>3</sub>As

Concepts

Abstract