Concepedia

Self-Assembly of a Macrocyclic Dinuclear Pd(II)–Phosphine Complex

Makoto Fujita, Jun Yazaki, T. KURAMOCHI, Katsuyuki Ogura

Bulletin of the Chemical Society of Japan · 1993 · 22 citations · 8 references

DOI

Concepts

Abstract

Abstract Reaction of a diphosphine ligand, bis[4-[2-(diphenylphosphino)ethyl]phenyl] ether (1) with Na2PdCl4 gave a macrocyclic dinuclear complex [PdCl2(μ-1)]2 (2) in a 58% isolated yield. The formation of 2 appears to result from a spontaneous self-assembly process under thermodynamic control, and thus, no special technique such as a high-dilution method was needed.

References

8

Preparation of a macrocyclic polynuclear complex, [(en)Pd(4,4'-bpy)]4(NO3)8 (en = ethylenediamine, bpy = bipyridine), which recognizes an organic molecule in aqueous media

Makoto Fujita, Jun Yazaki, Katsuyuki Ogura · Journal of the American Chemical Society · 1990 · 801 citations

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Complexation of Neutral Molecules by Cyclophane Hosts

François Diederich · Angewandte Chemie International Edition in English · 1988 · 410 citations

, , +12

Palladium(II)-directed assembly of macrocyclic dinuclear complexes composed of (en)Pd2+ and bis(4-pyridyl)-substituted bidentate ligands. Remarkable ability for molecular recognition of electron-rich aromatic guests

Makoto Fujita, Satoshi Nagao, Masashi Iida et al. · Journal of the American Chemical Society · 1993 · 221 citations

, , +12

Macrocylic polynuclear complexes [(en)M(4,4′-bpy)]4(NO3)81 (M = Pd or Pt) as “Inorganic Cyclophane.” Their Ability for Molecular Recognition

Makoto Fujita, Jun Yazaki, Katsuyuki Ogura · Tetrahedron Letters · 1991 · 113 citations

, , +4

Arylenebis(tertiary phosphines) and -(phosphinic acids)

Roger A. Baldwin, Ming Cheng · The Journal of Organic Chemistry · 1967 · 71 citations

, , +9