Concepedia

Syntheses and molecular structure of organo-group 13 metal carbene complexes

Xiao-Wang Li, Jianrui Su, Gregory H. Robinson

Chemical Communications · 1996 · 66 citations · 9 references

DOI

Concepts

Abstract

Trimethylaluminium or trimethylgallium reacts with 1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene 1 to afford the first organo-group 13 metal carbenes 2 (M = Al 2a, Ga 2b), which are characterized by elemental analyses, IR, 1H and 13C NMR spectroscopy, and single-crystal X-ray diffraction.

References

9

A stable crystalline carbene

Anthony J. Arduengo, Richard L. Harlow, Michael Kline · Journal of the American Chemical Society · 1991 · 4.1K citations

, , +4

Electronic stabilization of nucleophilic carbenes

Anthony J. Arduengo, H. V. Rasika Dias, Richard L. Harlow et al. · Journal of the American Chemical Society · 1992 · 1.1K citations

, , +6

Preparation, Structure, and Reactivity of 1,3,4‐Triphenyl‐4,5‐dihydro‐1<i>H</i>‐1,2,4‐triazol‐5‐ylidene, a New Stable Carbene

Dieter Enders, Klaus Breuer, Gerhard Raabe et al. · Angewandte Chemie International Edition in English · 1995 · 536 citations

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Nucleophilic Carbenes: An Incredible Renaissance

Manfred Regitz · Angewandte Chemie International Edition in English · 1996 · 278 citations

, , +14

A stable carbene-alane adduct

Anthony J. Arduengo, H. V. Rasika Dias, Joseph C. Calabrese et al. · Journal of the American Chemical Society · 1992 · 209 citations

, , +4