Transition dipole moment of the .nu.3 band of CH3

Abstract

The transition dipole moment of the ν3 band of the methyl radical has been measured for the first time. A new discharge laser amplitude double modulation method with a difference frequency laser spectrometer and a hollow cathode discharge cell has been used. The CH3 concentration has been estimated from the absorption decay when the discharge is turned off. The transition dipole moment is found to be μν3 = 0.029 ± 0.005 D. © 1994 American Chemical Society.