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<i>N</i>-(9-(9-Phenylfluorenyl))homoserine-Derived Cyclic Sulfamidates: Novel Chiral Educts for the Synthesis of Enantiopure γ-Substituted α-Amino Acids
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Citations
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References
2001
Year
Oxygen NucleophilesHomoserine-derived Cyclic SulfamidatesEnantioselective SynthesisEngineeringBiochemistryNatural SciencesNovel Chiral EductsOrganic ChemistryStereoselective SynthesisChemistrySee TextAsymmetric CatalysisSynthetic ChemistryGamma-substituted Alpha-amino AcidsBiomolecular Engineering
(4S)-tert-Butyl 2,2-dioxo-3-PhF-1,2,3-oxathiazainane-4-carboxylate reacted effectively with nitrogen, sulfur, and oxygen nucleophiles to provide enantiopure (>97% ee) gamma-substituted alpha-amino acids. Reaction: see text.
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