Angewandte Chemie International Edition · 2009 · 162 citations · 37 references
Electron by electron: Beta-diketiminato nickel(I) complex fragments are capable of activating N(2) through coordination. The resulting complex can be reduced in two single-electron steps, which further activates the N-N bond. The picture shows the structure of the singly reduced complex with mu-eta(1):eta(1)-bound N(2).
37
Studies of Low-Coordinate Iron Dinitrogen Complexes
Jeremy M. Smith, A.R. Sadique, Thomas R. Cundari et al. · Journal of the American Chemical Society · 2005 · 320 citations · Full text
A Terminal Ni(III)−Imide with Diverse Reactivity Pathways
E. Kogut, Heather L. Wiencko, Libei Zhang et al. · Journal of the American Chemical Society · 2005 · 320 citations