Publication | Closed Access
First Synthesis of Perfluorinated Corrole and Its MnO Complex
143
Citations
47
References
2003
Year
Materials ScienceInorganic ChemistryChemical EngineeringMno ComplexEngineeringCatalytic OxidationPerfluorinated Manganese CorrolateFluorous SynthesisOrganic ChemistryOrganometallic CatalysisCatalysisChemistryHalogenationInorganic MaterialInorganic SynthesisCatalytic SynthesisExcellent Reactivity
A novel perfluorinated corrole, 2,3,7,8,12,13,17,18-octafluoro-5,10,15-tris(pentafluorophenyl)corrole, and its manganese(III) and oxomanganese(V) derivatives have been synthesized. The perfluorinated manganese corrolate exhibited excellent reactivity and stability in the catalytic oxidation of alkenes with iodosylbenzene.
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