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Facile Allylation of <i>N</i>‐Boc and <i>N</i>‐Cbz Imines with Allyltrichlorosilane promoted by DMF
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Citations
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References
2008
Year
Various N‐bocFacile AllylationCross-coupling ReactionEngineeringBiochemistryFinancial SupportNatural SciencesDiversity-oriented SynthesisOrganic ChemistryAbstract Facile AllylationOrganometallic CatalysisChemistryHeterocycle ChemistryHalogenationEnantioselective SynthesisBiomolecular Engineering
Abstract Facile allylation of various N‐Boc and N‐Cbz imines with allyltrichlorosilane has been effected using N,N‐dimethylformamide (DMF) as the activator. The N‐Boc and N‐Cbz homoallylic amines were obtained in good to high yields under mild conditions. Keywords: Allylationallyltrichlorosilane N‐Boc imines N‐Cbz iminesDMF Acknowledgment We are grateful for financial support from the National Natural Science Foundation of China (Projects 20402014 and 20672107).
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