Publication | Closed Access
The Synthesis and Evaluation of New α-Hydrogen Nitroxides for ‘Living’ Free Radical Polymerization
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Citations
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References
2005
Year
Chemical EngineeringPolymerization ReactionsEngineeringMacromolecular EngineeringNitroxide TipnoRadical (Chemistry)Polymer ScienceNew α-Hydrogen NitroxidesCatalytic SynthesisOrganic ChemistryCatalysisChemistryPolymerization KineticsNitroxide-mediated Radical PolymerizationPolymer ReactionPolymer ChemistryPolymer SynthesisPolymers
Three N-alkoxyamines were synthesized for use in nitroxide-mediated radical polymerization. Upon thermolysis, they generate new acyclic α-hydrogen nitroxides: one adamantyl substituted and two diol-containing nitroxides. The initiators were tested in polymerization reactions in direct comparison with the initiator derived from the nitroxide TIPNO.
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