The Influence of Morphology on High‐Performance Polymer Field‐Effect Transistors

Abstract

The influence of molecular packing on the performance of polymer organic field-effect transistors is illustrated in this work. Both close π-stacking distance and long-range order are important for achieving high mobilities. By aligning the polymers from solution, long-range order is induced, yielding hole mobilities of up to µsat = 1.4 cm2 V−1 s−1 and current on/off ratios Ion/Ioff of 105. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.