Decay of excited molecules in absorbing planar cavities

Abstract

The decay rate of an excited molecule (atom) embedded in a dispersive and absorbing planar cavity is derived by using a recently obtained compact form of the Green's function for a multilayer. As a by-product, a hint is provided for a straightforward extension of the results obtained for lossless cavities of other shapes to the corresponding absorbing cavities. The decay rate in an absorbing cavity consists of the spontaneous emission rate and of the nonradiative rates caused by the near-field interaction of the molecule with the cavity medium and, for nearby molecules, with the cavity mirrors. Only the spontaneous emission rate is satisfactorily described in the macroscopic approach adopted. The theory is applied to an analysis of the effects of the weak cavity absorption on the decay rate in a dielectric microcavity formed by two metallic mirrors. As expected, dissipation in the cavity medium spoils the conditions for controlled spontaneuos emission and strongly suppresses the intensity of spontaneous emission. However, its effect on the spontaneous emission rate is much less pronounced.