Water-Induced Degradation of Polymer Solar Cells Studied by H₂¹⁸O Labeling

TLDR

Water-induced degradation of polymer solar cells using P3HT or MEHPPV active layers was investigated. The study employed bulk heterojunction devices of P3HT or MEHPPV with PCBM, applying H₂¹⁸O and TOF‑SIMS to map water‑induced changes, comparing different active materials, illumination, and humidity conditions, and contrasting the results with prior ¹⁸O₂ studies. Water behaved similarly to, but not identically with, molecular oxygen in degrading the devices.

Abstract

Water-induced degradation of polymer photovoltaics based on the active materials poly(3-hexylthiophene) (P3HT) or poly[2-methoxy-5-(2′-ethylhexyloxy)-1,4-phenylenevinylene] (MEHPPV) was studied. The solar cell devices comprised a bulk heterojunction formed by the active material and [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) in a standard device geometry. The use of H218O in conjunction with time-of-flight secondary ion mass spectrometry enabled mapping of the parts of the device that were induced by water. A comparison was made between the two active materials and between devices that were kept in the dark and devices that had been subjected to illumination under simulated sunlight. Devices that were exposed to ambient humidity were compared to devices exposed to saturated humidity. Finally, a comparison was made between results obtained using H218O and earlier work involving 18O2. Water was found to have behavior similar to but not identical with molecular oxygen.