A local composition model for the excess Gibbs energy of aqueous electrolyte systems

Abstract

Abstract The electrolyte nonrandom two‐liquid (NRTL) model proposed by Chen et al. (1982) is generalized to represent the excess Gibbs energy of aqueous multicomponent electrolyte systems. Using only binary parameters, the model correlates and predicts the deviation from ideality of aqueous multicomponent electrolyte systems over the entire range of temperature and concentration.