Concepedia

PALLADIUM-CATALYZED DOUBLE CARBONYLATION REACTIONS OF ARYL HALIDES AFFORDING α-KETO ESTERS

Fumiyuki Ozawa, Nobuo Kawasaki, Takakazu Yamamoto, Akio Yamamoto

Chemistry Letters · 1985 · 43 citations · 3 references

DOI

Concepts

Abstract

Abstract Various aryl iodides can be converted into α-keto esters in reactions with carbon monoxide and alcohols in the presence of tertiary amines and catalytic amounts of tertiary phosphine-coordinated palladium complexes.

References

3

Catalytic double carbonylation of organohalogen compounds promoted by palladium complexes

Fumiyuki Ozawa, Hidehiko Soyma, Takakazu Yamamoto et al. · Tetrahedron Letters · 1982 · 139 citations

, , +16

Palladium(II)-catalyzed double carbonylation of organic halides in the presence of amines: α-Ketoamide synthesis

Toshiaki Kobayashi, Masato Tanaka · Journal of Organometallic Chemistry · 1982 · 119 citations

, , +6

Preparation of trans-Pd(COCOR)Cl(PMePh2)2 complexes (R = Ph and Me) and their reactivities relative to double carbonylation promoted by palladium

Fumiyuki Ozawa, Takeshi Sugimoto, Takakazu Yamamoto et al. · Organometallics · 1984 · 70 citations

, , +12