Electrides: Ionic Salts with Electrons as the Anions

Abstract

Electrides are ionic compounds that have alkali metal cations complexed by a crown ether or cryptand, with trapped electrons as counterions. The crystal structures and properties of two electrides illustrate the diversity that is encountered. One Cs(+) (18-crown-6)(z)e(-), has relatively isolated, trapped electrons apparently centered at each anionic site. It has a low conductivity consistent with electron localization, with an activation energy for conductivity of at least 0.45 electron volt. The other, K(+) (cryptand[2.2.2])e(-), has electron pairs trapped in an elongated cavity in a singlet ground state, but there is also a thermally accessible paramagnetic state available. This electride is much more conducting, with an activation energy of only 0.02 electron volt.