Publication | Closed Access
Rational Design of Open-Framework Coordination Solids − Synthesis and Structure of [Co5(OH)2{1,2,4,5-(O2C)4C6H2}2(H2O)4]·xH2O
64
Citations
0
References
2001
Year
Materials ScienceInorganic ChemistryChemical EngineeringEngineeringOpen-framework Coordination SolidsRational DesignSelf-assemblyCovalent Bonded FrameworkCoordination ComplexHydrothermal SynthesisCatalysisCoordination PolymerChemistryCatalyst PreparationMetal-organic PolyhedronCrystallographyInorganic SynthesisUnsaturated Metal Ions
A strategy for preparing open-framework coordination solids by hydrothermal synthesis has been developed and tested by the synthesis of a new porous cobalt carboxylate which can be dehydrated by heating to give a material with coordinatively unsaturated metal ions.