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A New Selective Method for the Homolytic Alkylation and Carboxylation of Quinones by Monoesters of Oxalic Acid
21
Citations
3
References
1992
Year
Cross-coupling ReactionEnantioselective SynthesisEngineeringOxalic AcidSelective SubstitutionNew Selective MethodRadical (Chemistry)Homolytic AlkylationAbstract AlkylOrganic ChemistryCatalysisDeoxygenationChemistryAsymmetric CatalysisSynthetic ChemistryAlkoxycarbonyl RadicalsBiomolecular Engineering
Abstract Alkyl and alkoxycarbonyl radicals were generated by oxidative decarboxylation of oxalic acid monoesters by persulfate; they were then utilized for the selective substitution of quinones.
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