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A New Ru-Catalyzed Cascade Reaction Forming Polycyclic Cyclohexadienes from 1,6-Diynes and Alkenes
102
Citations
6
References
2006
Year
Chemical EngineeringCross-coupling ReactionEngineeringHeterocyclicAlkene MetathesisBicyclic 1,3-CyclohexadienesOrganic ChemistryNew Cascade ReactionRu-catalyzed AdditionCatalysisOrganometallic CatalysisChemistry
Functionalized bicyclic 1,3-cyclohexadienes can be easily prepared by a new cascade reaction which involves the Ru-catalyzed addition of acyclic alkenes to 1,6-diynes to give (Z)-hexatrienes, followed by a pure thermal 6e-pi electrocyclization.
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