Recent Advances in the Synthesis and Catalytic Applications of Pillared Clays

TLDR

Recent advances have introduced new methods for preparing pillared interlayered clays (PILCs), varying parameters such as clay type, intercalating solution, intercalation process, and drying/calcination steps. This article reviews the latest results obtained by modifying the chemical aspects of PILC synthesis. The review covers mixed‑cation pillaring, coordination or organometallic compounds, polymers and surfactants, acid‑activated clay pillaring, acidity enhancement, and scale‑up strategies for industrial production. Recent developments show PILCs are increasingly employed as catalytic supports, highlighting their expanding use in catalysis.

Abstract

New methods have been developed in recent years that are now being successfully applied in the preparation of pillared interlayered clays (PILCs). Variations in the procedures concern different parameters involved in the synthesis, such as the starting clay, the intercalating solution, the intercalation process, and the drying and calcination steps of the pillared solids, among others. In the present article, the latest results obtained when introducing modifications in the chemical aspects of PILC synthesis are reviewed. These include (1) pillaring with mixed solutions containing two or more cations, (2) using coordination or organometallic compounds, (3) using polymers and surfactants, (4) pillaring of acid-activated clays, and (5) enhancement of PILC acidity. A separate section is devoted to the specific features of preparing these solids in amounts large enough to make their manufacture on an industrial scale economically feasible. Recent developments in the catalytic applications of PILCs are also reviewed, with emphasis on the progressively more extended use of these materials as catalytic supports.