Acta Crystallographica Section E Structure Reports Online · 2008 · 46 citations · 4 references
Natural SciencesChemistryCrystal StructureOrganic ChemistrySupramolecular ChemistryCoordination ChemistryCrystal ChemistryHeterocyclic ChemistryMolecular StructureMolecular SymmetryDihedral AngleHydrogen Bond OrientationHydrogen-bond NetworksHydrogen-bonded Networks
In the title compound, C(14)H(10)ClN(3)O(3)·H(2)O, the benzohydrazide group is not planar and the mol-ecule exists in a cis configuration with respect to the methyl-idene unit. The dihedral angle between the two substituted benzene rings is 38.7 (3)°. In the crystal structure, mol-ecules are linked by O-H⋯O, O-H⋯N and N-H⋯O hydrogen bonds into a two-dimensional network parallel to the (100) plane. The crystal structure is further stabilized by weak C-H⋯O inter-actions.
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George M. Sheldrick · Acta Crystallographica Section A Foundations of Crystallography · 2007 · 87.4K citations · Full text