Concepedia

Bicyclic guanidinate compounds of magnesium and their activity as pre-catalysts in the Tishchenko reaction

Benjamin M. Day, N.E. Mansfield, Martyn P. Coles, Peter B. Hitchcock

Chemical Communications · 2011 · 65 citations · 33 references

DOI

Concepts

Abstract

A synthetic route to magnesium guanidinate compounds that avoids ligand redistribution is reported; selected derivatives are active pre-catalysts in the dimerization of aldehydes.

References

33

Synthesis, structure, and spectroscopic properties of copper(<scp>II</scp>) compounds containing nitrogen–sulphur donor ligands; the crystal and molecular structure of aqua[1,7-bis(N-methylbenzimidazol-2′-yl)-2,6-dithiaheptane]copper(<scp>II</scp>) perchlorate

Anthony W. Addison, T. Nageswara Rao, J. Reedijk et al. · Journal of the Chemical Society Dalton Transactions · 1984 · 9.2K citations

, , +10

Stable Magnesium(I) Compounds with Mg-Mg Bonds

S.P. Green, Cameron Jones, Andreas Stasch · Science · 2007 · 795 citations

The coordination chemistry of the amidine ligand

James Barker, Melvyn Kilner · Coordination Chemistry Reviews · 1994 · 678 citations

, , +2

The coordination chemistry of guanidines and guanidinates

Philip J. Bailey, S. Pace · Coordination Chemistry Reviews · 2001 · 510 citations

, , +1

N-silylated benzamidines: versatile building blocks in main group and coordination chemistry

Frank T. Edelmann · Coordination Chemistry Reviews · 1994 · 492 citations

, , +4