Concepedia

Rhodium‐Mediated Formation of Peroxides from Dioxygen: Isolation of Hydroperoxo, Silylperoxo, and Methylperoxo Intermediates

Marcel Ahijado, Thomas Braun, D. Noveski, N. Kocher, Beate Neumann, Dietmar Stalke, Hans‐Georg Stammler

Angewandte Chemie International Edition · 2005 · 76 citations · 51 references

DOI

Concepts

Abstract

Out of thin air, a rhodium complex converts molecular oxygen into hydrogen peroxide, bis(trimethylsilyl) peroxide, and methyl hydroperoxide. Intermediate η1-hydroperoxo and η1-silylperoxo, and η1-methylperoxo complexes have been isolated. Another η1-methylperoxo (see picture) and an η1-hydroperoxo complex have been characterized by X-ray crystallography.

References

51

Crystal handling at low temperatures

Thomas Kottke, Dietmar Stalke · Journal of Applied Crystallography · 1993 · 1.2K citations · Full text

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Transition-metal complexes for liquid-phase catalytic oxidation: some aspects of industrial reactions and of emerging technologies

Jean‐Marie Brégeault · Dalton Transactions · 2003 · 366 citations

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A Well‐Defined Complex for Palladium‐Catalyzed Aerobic Oxidation of Alcohols: Design, Synthesis, and Mechanistic Considerations

David R. Jensen, Mitchell J. Schultz, Jaime A. Mueller et al. · Angewandte Chemie International Edition · 2003 · 297 citations

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Characterization of Peroxo and Hydroperoxo Intermediates in the Aerobic Oxidation of <i>N</i>-Heterocyclic-Carbene-Coordinated Palladium(0)

Michael M. Konnick, Ilia A. Guzei, Shannon S. Stahl · Journal of the American Chemical Society · 2004 · 204 citations

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Mechanistic Characterization of Aerobic Alcohol Oxidation Catalyzed by Pd(OAc)<sub>2</sub>/Pyridine Including Identification of the Catalyst Resting State and the Origin of Nonlinear [Catalyst] Dependence

Bradley A. Steinhoff, Ilia A. Guzei, Shannon S. Stahl · Journal of the American Chemical Society · 2004 · 201 citations

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