Collection of Czechoslovak Chemical Communications · 2001 · 31 citations · 12 references
Organic Charge-transfer CompoundPhenyl DerivativesEngineeringPhysicsNatural SciencesOrganic ChemistryDipole MomentComputational ChemistryChemistryQuantum ChemistryMolecule-based MaterialPhenyl GroupSpectra-structure CorrelationCharge Distribution
The dipole moment of 1,2-dicarba- closo -dodecaborane is oriented with the positive end towards the carbon atoms as follows from measurements on phenyl derivatives with variable substituents. Towards the phenyl group, the substituent 1,2-C 2 B 10 H 11 behaves as a weak electron acceptor.
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Alan E. Reed, Robert B. Weinstock, Frank Weinhold · The Journal of Chemical Physics · 1985 · 9.7K citations