Angewandte Chemie International Edition · 2011 · 269 citations · 68 references
Natural SciencesChemistryMaterials ScienceInorganic ChemistryMagnetic MaterialsMaterials ChemistryCluster ChemistryFerromagnetic MaterialsMagnetic Properties Of SolidsMagnetism In SolidsMagnetism Of Inorganic CompoundsMagnetism Of Transition Metal ComplexesMolecular MagnetismMolecular MagnetsSingle-molecule MagnetismSingle-molecule Magnets
POMs, magnets, and Co: The tetrameric 36-tungsto-8-phosphate [{Co4(OH)3PO4}4(PW9O34)4]28− containing 16 cobalt(II) centers was prepared by a simple, one-pot synthetic procedure. The {Co16(OH)12(PO4)4}8+ core (see picture) exhibits single-molecule magnetic behavior.
68
A Fast Soluble Carbon-Free Molecular Water Oxidation Catalyst Based on Abundant Metals
Qiushi Yin, Jeffrey Miles Tan, Claire Besson et al. · Science · 2010 · 1.4K citations