Concepedia

The Hosomi–Sakurai allylation in hexafluoroisopropanol: solvent promotion effect

Svetlana P. Panchenko, Sofia A. Runichina, Vasily V. Tumanov

Mendeleev Communications · 2011 · 10 citations · 9 references

DOI

Concepts

Abstract

Hydrogen bond donating capacity of hexafluoroisopropanol was shown to be responsible for both the formation of its stoichiometric complexes with aldehydes and acetals and subsequent facilitation of their reactions with allylsilanes.

References

9

Fluorinated Alcohols as Solvents, Cosolvents and Additives in Homogeneous Catalysis

Ivan A. Shuklov, Armin Börner, Natalia V. Dubrovina · Synthesis · 2007 · 416 citations

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Unveiling the “Booster Effect” of Fluorinated Alcohol Solvents:  Aggregation-Induced Conformational Changes and Cooperatively Enhanced H-Bonding

Albrecht Berkessel, Jens A. Adrio, D. Huttenhain et al. · Journal of the American Chemical Society · 2006 · 361 citations

, , +16

Hydrogen Bonding in Fluoro Alcohols

William J. Middleton, R. V. Lindsey · Journal of the American Chemical Society · 1964 · 241 citations

, , +10

Dramatic Acceleration of Olefin Epoxidation in Fluorinated Alcohols:  Activation of Hydrogen Peroxide by Multiple H-Bond Networks

Albrecht Berkessel, Jens A. Adrio · Journal of the American Chemical Society · 2006 · 209 citations

, , +16

Hydrogen‐Bonding Catalysts Based on Fluorinated Alcohol Derivatives for Living Polymerization

Olivier Coulembier, Alshakim Nelson, Andrew N. Hollenbeck et al. · Angewandte Chemie International Edition · 2009 · 114 citations

, , +10