Journal of the American Ceramic Society · 1998 · 26 citations · 17 references
Natural SciencesMaterials EngineeringMaterials ScienceMaterials CharacterizationRheologyThermodynamicsGlass MaterialsStress RelaxationThermal Properties Of MaterialsViscoelastic BehaviorViscoelastic PropertiesBrillouin ScatteringElastic ConstantsGlass TransitionGlass Transition BehaviorGlass Transition TemperatureStress Relaxation MechanismsTemperature DependenceThermorheological Behavior
The high‐frequency viscoelastic behavior of a soda‐lime‐silica glass has been investigated using the Brillouin scattering technique. The temperature dependence of instantaneous elastic constants and very short‐time relaxation mechanisms have been measured in a temperature range between 100° and 1000°C. Variations in the elastic constants in the transition region are significant, and have to be taken into account for numerical computations of tempering and annealing of glasses. A complex thermorheological behavior is observed for very fast relaxation mechanisms in the transition range, whereas intermediate and slow relaxation mechanisms exhibit a simple thermorheological behavior. The viscoelastic behavior of this glass can be adequately represented by assuming a different thermorheological behavior in the alpha‐ and β‐relaxation regimes.
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Viscoelastic Properties of Polymers.
Maurice L. Huggins · Journal of the American Chemical Society · 1961 · 392 citations