3D Nanostar Dimers with a Sub‐10‐nm Gap for Single‐/Few‐Molecule Surface‐Enhanced Raman Scattering

Manohar Chirumamilla, Andréa Toma, Gobind Das, Remo Proietti Zaccaria, Roman Krahne, Eliana Rondanina, Marco Leoncini, Carlo Liberale, Francesco De Angelis, Enzo Di Fabrizio

Advanced Materials · 2014 · 305 citations · 42 references

Concepts

Abstract

Plasmonic nanostar-dimers, decoupled from the substrate, have been fabricated by combining electron-beam lithography and reactive-ion etching techniques. The 3D architecture, the sharp tips of the nanostars and the sub-10 nm gap size promote the formation of giant electric-field in highly localized hot-spots. The single/few molecule detection capability of the 3D nanostar-dimers has been demonstrated by Surface-Enhanced Raman Scattering. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.

References

42