Organic Letters · 2010 · 54 citations · 29 references
Effective Decarboxylative Cross-couplingCross-coupling ReactionEngineeringSeveral Conjugated Oligomers3,4-Propylenedioxypyrrole-based Conjugated OligomersConjugated PolymerOrganic ChemistryStereoselective SynthesisChemistryLow SensitivityAsymmetric CatalysisSynthetic ChemistryEnantioselective SynthesisBiomolecular Engineering
An effective decarboxylative cross-coupling involving a 3,4-dioxypyrrole is reported. Several conjugated oligomers were synthesized in high yields using various aryl bromides. No copper salt or other transmetalating agent was required. The reaction conditions employed displayed relatively low sensitivity toward the presence of water.
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Norio Miyaura, Akira Suzuki · Journal of the Chemical Society Chemical Communications · 1979 · 1.1K citations