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Bissilyl Ketone; A Convenient Method for the Synthesis and Its Pd(0) Catalyzed Reaction with Alkenes and Alkynes
36
Citations
7
References
1996
Year
Chemical EngineeringEnantioselective SynthesisEngineeringCross-coupling ReactionBissilyl KetoneBissilyl Ketone AcetalOrganic ChemistryBis-silylated ProductsCatalysisOrganometallic CatalysisChemistryAsymmetric CatalysisA Convenient Method
Abstract A convenient method for the preparation of a bissilyl ketone is developed via a bissilyl ketone acetal as its percursor. The bissilyl ketone reacts with electron deficient alkynes and alkenes in the presence of Pd(0) catalyst to give bis-silylated products.
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