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Studies on the reactivity of 2-furylhydroxymethylphosphonates: synthesis of 1-oxo-4-hydroxycyclopent-2-en-5-ylphosphonates
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1987
Year
Natural Product SynthesisBioorganic ChemistryDirect PreparationBiochemistryProstaglandin-related CompoundsNatural SciencesOrganic ChemistryStereoselective SynthesisChemistryPharmacologySynthetic ChemistryEnantioselective SynthesisUnknown Phosphonate-containing Cyclopentenones
Starting from 2-furylhydroxymethylphosphonates (1), a facile and direct preparation of the previously unknown phosphonate-containing cyclopentenones (5), potential new synthons in the elaboration of rethrolone- and prostaglandin-related compounds, is described.